By Noyes W

Content material: Advances in Photochemistry; Contents; hugely complicated Photochemical Mechanisms; The Kinetics and Mechanism of Photochemical Oxidation of Aldehydes by way of Molecular Oxygen; Singlet and Triplet States: Benzene and easy fragrant Compounds; Photochemical Rearrangements of Conjugated Cyclic Ketones : the current kingdom of Investigations; Photochemistry of Conjugated Dienes and Trienes; The Reactions of Sulfur Atoms; a few Photochemical alterations of Polyenic Compounds; The Photolysis of the Diazirines; writer Index; topic Index; Cumulative Index

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Uk Many different plant species synthesise triterpenoid saponins as part of their normal programme of growth and development. Examples include plants that are exploited as sources of drugs, such as liquorice and ginseng, and also crop plants such as legumes and oats. Interest in these molecules stems from their medicinal properties, antimicrobial activity, and their likely role as determinants of plant disease resistance. Triterpenoid saponins are synthesised via the isoprenoid pathway by cyclization of 2,3-oxidosqualene to give primarily oleanane (bamyrin) or dammarane triterpenoid skeletons.

46 5 References . . . . . . . . . . . . . . . . 47 List of Abbreviations aAS bAS CS DS EST LS LuP OSC PCR SC a-Amyrin synthase b-Amyrin synthase Cycloartenol synthase Dammarenediol synthase Expressed sequence tag Lanosterol synthase Lupeol synthase Oxidosqualene cyclase Polymerase chain reaction Squalene-hopene cyclase 1 Introduction Collectively plants synthesise a diverse array of secondary metabolites, either as part of normal growth and development or in response to pathogen attack or stress.

Deutscher Biotechnologie Report, Stuttgart 51. Müller A, Lucas P, MacCabe B, Mendoza-Vega O et al. (1998) European Life Sciences 98 – Continental Shift, Ernst & Young International, London 52. Müller A, Powlett Smith W, Mendoza-Vega O, MacCabe B et al. (2000) Evolution – Ernst & Young’s Seventh Annual European Life Sciences Report 2000, Ernst & Young International, London 53. Goffeau A, Barrell BG, Bussey H, Davis RW et al. (1996) Science 274:546, 563 54. Blattner FR, Plunkett G, Bloch CA, Perna NT et al.

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Advances in Photochemistry by Noyes W

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